OXAMMONIUM HYDROCHLORIDE

PRODUCT IDENTIFICATION

CAS NO. 7803-49-8 (Parent), 5470-11-1 (HCl)

OXAMMONIUM HYDROCHLORIDE 

EINECS NO. 7803-49-8, 226-798-2
FORMULA H2NOH·HCl
MOL WT. 69.49
H.S. CODE 2825.10
TOXICITY Oral rat LD50; 41mg/kg
SYNONYMS Hydroxylamine chloride; Hydroxylamine chloride (1:1);
Hydroxyammonium chloride; Oxammonium Hydrochloride; Cloruro de hidroxilamonio; Chlorure d'hydroxylammonium;
SMILES
 

CLASSIFICATION

 

PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL STATE white crystals
MELTING POINT 155 - 157 C
BOILING POINT Decomposes
SPECIFIC GRAVITY 1.67
SOLUBILITY IN WATER  
AUTOIGNITION

 

pH  
VAPOR DENSITY  
NFPA RATINGS  

REFRACTIVE INDEX

 

FLASH POINT

 

STABILITY Stable under ordinary conditions

GENERAL DESCRIPTION & APPLICATIONS

Hydroxylamine is a white crystalline compound containing nitrogen with the formula of NH2OH and is therefore an ammonia (NH3) like compound. In the nature, hydroxylamine is an biological intermediate in the nitrification (biological oxidation of ammonia with oxygen into nitrite ) and in the anammox (biological oxidation of nitrite and ammonium into dinitrogen gas) which are important in the nitrogen cycle in soil and in wastewater treatment. Hydroxylamine is obtained commercially by acid hydrolysis of nitroparaffins or by the modified reduction of nitric acid. It is used as a powerful reducing agent in photography and in organic synthesis. It converts aldehydes (and ketones) to oximes (caprolactam), and acid chlorides to hydroxamic acids. It is used as a catalyst or inhibitor in polymerization processes. It is used in enzyme reactivation. It is used as an antioxidant in fatty acids and soaps. The nitrate form of hydroxylammonium is used as a rocket fuel which is burned with an oxidizer to produce thrust. Hydroxylamine tends to be explosive when heated. Its derivatives in the form of salts are more stable to be used and handled. Hydroxylamine Hydrochloride is used as an auxiliary in photographic industry to prevent discolouration. It is a polymerization inhibitor or free radical scavenger against solid bond monomers such as olefin, styrene, butadiene, isoprene and divinylbenzene. It is also used in rubber synthesis processes as a non-discoloring short stoppers. Diethylhydroxylamine has the property of oxygen scavenging and used in water treatment chemical formulation to prevent corrosion. It is used as an auxiliary in photographic industry to prevent discolouration. It is a vapour phase polymerization inhibitor against solid bond monomers such as olefin, styrene, butadiene, isoprene and divinylbenzene. It is used as a stabilizer for phenolics. It is used as an intermediate for pharmaceuticals and water treatment chemicals. It is also used as a raw material of silicon sealant and coating materials. Hydroxylammonium salts find applications in the field of :

  • Organic synthesis: preparation of oximes, hydroxamic acids from carboxylic acids, N- and O- substituted hydroxyamines, and addition reactions of carbon-carbon solid bond.
  • Surface treatments: preparation of anti-skinning agents, corrosion inhibitors, meta; cleaner additive
  • Starting material for pharmaceuticals and agrochemicals manufacturing
  • Rubber and plastic industry: antioxidant, vulcanization accelerator, radical scavenger.
  • Textile industry: fixative for textile dyes, auxiliary in some dyeing processes. bleaching
  • Metallurgy: Metal extraction and flotation aid
  • Aantioxidant in fatty acids and soaps
  • Photographic auxiliary as a stabilizer of colour and emulsion additive for colour films.
SALES SPECIFICATION

APPEARANCE

white crystals

ASSAY

99.0% min

WATER

0.1% max

FREE HCl

0.5% max

TRANSPORTATION
PACKING 25kgs in bag
HAZARD CLASS 8 (Packing Group: II)
UN NO. 2923
OTHER INFORMATION
Hazard Symbols: XN N, Risk Phrases: 22-36/38-43-50-48/22, Safety Phrases: 22-24-37-61