| BIS(PINACOLATO)DIBORON | ||
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PRODUCT IDENTIFICATION |
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| CAS NO | 73183-34-3 |
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| EINECS NO. | ||
| FORMULA | C12H24B2O4 | |
| MOL WT. | 253.94 | |
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H.S. CODE |
2934.99.9000 | |
| TOXICITY | ||
| SYNONYMS | 4,4,4',4',5,5,5',5'-Octamethyl-2,2'-bi-1,3,2-dioxaborolane; | |
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DERIVATION |
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CLASSIFICATION |
Boronic acid derivatives, Borylation reagents, Organometallic reagents. |
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PHYSICAL AND CHEMICAL PROPERTIES |
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| PHYSICAL STATE |
white to off-white powder | |
| MELTING POINT | 137 - 140 C | |
| BOILING POINT |
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| SPECIFIC GRAVITY | ||
| SOLUBILITY IN WATER | ||
| pH | ||
| VAPOR DENSITY | ||
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NFPA RATINGS |
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AUTOIGNITION |
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REFREACTIVE INDEX |
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| FLASH POINT | ||
| STABILITY | Stable under ordinary conditions. | |
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APPLICATIONS |
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Reagent used for the cis-vicinal diborylation of acetylenes and olefins with Pt catalysis; borylation of aromatics by Pd catalysis. Substrate used in a new palladium-catalyzed cyclization of 1,6-enynes leading to homoallylic alkylboronates. Used to construct a tetramethylpyrrolidine nitroxide scaffold for the synthesis of paramagnetic heterocycles by Suzuki coupling. Used as a specific functionalization or linear alkanes to form alkylboranes.An air-stable crystalline solid reagent for single step synthesis of boronic esters Pd-catalyzed one step conversion allowing access to boronic acid derivatives without protection of functionalities such as ester, ketone, cyano or nitro groups. |
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| SALES SPECIFICATION | ||
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APPEARANCE |
white to off-white powder | |
| ASSAY |
98.0% min | |
| MELTING POINT |
137 - 140 C | |
| TRANSPORTATION | ||
| PACKING | ||
| HAZARD CLASS |
Not dangerous goods | |
| UN NO. | ||
| OTHER INFORMATION | ||
| Hazard Symbols: XI, Risk Phrases: 36/37/38, Safety Phrases: 26-37/39 | ||
