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| 4,4'-DIAMINODIPHENYLAMINE-2'-SULFONIC ACID | ||
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PRODUCT IDENTIFICATION |
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| CAS NO. | 119-70-0 |
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| EINECS NO. | 204-344-4 | |
| FORMULA |
NH2C6H4NHC6H5SO3HNH2 | |
| MOL WT. | 279.31 | |
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H.S.CODE |
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| SMILES |
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| TOXICITY | ||
| SYNONYMS | 6-(p-Aminoanilino)metanilic acid; F.C. Acid; | |
| 4-(p-Aminoanilino)-3-sulfoaniline; 4,4'-Diamino-2-sulfodiphenylamine; 6-(p-Aminoanilino) Metanilic acid; 4,4'-Diaminodiphenylamine-2-sulfonic acid; 5-Amino-2-(p-aminoanilino) benzenesulfonic acid; ácido 5-amino-2-(p-aminoanilino)bencenosulfónico (Spanish); Acide 5-amino-2-(p-aminoanilino) benzènesulfonique (French); | ||
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CLASSIFICATION |
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PHYSICAL AND CHEMICAL PROPERTIES |
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| PHYSICAL STATE | dark blue to grey powder | |
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| SOLUBILITY IN WATER |
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| pH | ||
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| AUTOIGNITION |
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REFRACTIVE INDEX |
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| FLASH POINT |
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| STABILITY | Stable under ordinary conditions. | |
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APPLICATIONS |
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Sulfonic acid is a compound with general formula RSO2OH, where R is an aliphatic
or aromatic hydrocarbon. It is a derivative of sulfuric acid (HOSO2OH) where an
OH has been replaced by a carbon group or a compound where a hydrogen atom has
been replaced by treatment with sulfuric acid; for example, benzene is converted
to benzenesulfonic acid (water-soluble). Sulfonic acid has a sulfur atom bonded
to a carbon atom of a hydrocarbon and bonded also to three oxygen atoms, one of
which has been attached to a hydrogen atom. Sulfonic acid is acidic due to the
hydrogen atom, stronger than a carboxylic acid. Sulfonic acid is one of the most
important organo sulfur compounds in organic synthesis. Sulfonic acids are used
as catalysts in esterification, alkylation and condensation reactions.
Sulfonates are salts or esters of sulfonic acid. Sulfonic salts are soluble in
water. Sulfonic acid and its salts present in organic dyes provide useful
function of water solubility and or improve the washfastness of dyes due to
their capabiltity of binding more tightly to the fabric. They are widely used in
the detergent industry. Alkylbenzene sulfonic acid is the largest-volume
synthetic surfactant because of its relatively low cost, good performance, the
fact that it can be dried to a stable powder and the biodegradable environmental
friendliness. Sulfonate cleaners do not form an insoluble precipitates in hard
water. Sulfonic acid salts and esters are intermediates widely used in organic
synthesis and particularly phenolic compounds and cation exchange resins. They
are synthetic intermediate for a number of biologically active compounds and
pharmaceutical candidates such as sulfa drugs.
4,4'-Diaminodiphenylamine-2'-sulfonic acid is used as an intermediate for the synthesis of azo dyes, pigments and other chemical compounds. |
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| SALES SPECIFICATION | ||
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APPEARANCE |
dark blue to grey powder | |
| ASSAY (BY MASS) |
92.0% min | |
| INSOLUBLES | 0.5% max (in HCl) | |
| TRANSPORTATION | ||
| PACKING | 25kgs in bag | |
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| GENERAL DESCRIPTION OF AMINE |
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| Amine is a group of basic organic compounds derived by replacement of one (primary amines), two (secondary amines), or three (tertiary amines) of the hydrogen atoms in ammonia (NH3) by alkyl or aryl groups. Tertiary amines combine with one molecular proportion of an alkyl iodide to form quaternary ammonium salts in which a central nitrogen atom is joined to four organic radicals and one acid radical used as a corrosion inhibitor, emulsifying and antiseptic agents. Amines, like ammonia, are weak bases because the unshared electron pair of the nitrogen atom can form a coordinate bond with a proton. Amines react with acids to give salts and with acid anhydrides (or or ester ) to form amides. They react with halogenoalkanes to form longer chains. Low molecular amine names are formed by adding '-amine' as a suffix to the name of the parent compound. In substitutive nomenclature, the prefix 'amino-' is placed before the name of the parent compound to denote the fuctional group in high molecular amines. Synthetic amines are made mostly by reaction of alcohols with ammonia, catalyzed by metals( nickel or copper) or metal oxide at high temperature. Many methods have been devised for the synthesis of the amines; reacting ammonia with an alkyl halide and neutralizing the resulting alkyl ammonium salt with an alkali, e.g., sodium hydroxide. This procedure yields a mixture of primary, secondary, and tertiary amines that is easily separated into its three components by fractional distillation; boiling methyl isocyanate with caustic potash, heating the alkyl iodides with ammonia; reduction of nitriles with alcohol and sodium; heating the esters of nitric acid with alcoholic ammonia; reducing on nitro-paraffms; action of zinc and hydrochloric acid on aldehyde ammonias; reduction of the phenylhydrazones and oximes of aldehydes and ketones with sodium amalgam in the presence of alcohol and sodium acetate; action of dilute hydrochloric acid on the isonitriles; heating the mustard oils with a mineral acid, by the hydrolysis of the alkyl phthalimides. Primary amines contain the functional group -NH2 (called amino group) and are converted into secondary and tertiary amines if heated with alkyl or aryl iodides. Primary amines form various oxidation products violently with concentrated nitric acid. If the amines are acetylated, they form nitro derivatives with concentrated nitric acid. Primary amines form diazonium salts with nitrous acid in cold solution in the presence of excess of mineral acid. Or a diazoamine is obtained in absence of excess of acid. Other ractions; forming condensation products with aldehydes; forming anilides; forming alkyl thioureas; yielding isonitriles with alcoholic potash and chloroform. Aliphatic amines which have the lowest carbon content are water-soluble gases or liquids of low boiling point also readily soluble in water in case of the next low carbon content. But aliphatic amines which have the high carbon content are odourless solids of high boiling point and are insoluble in water. They are all bases and easily forms salts with the mineral acids and solid salts with the halogenoalkanes. Amine Salts are crystalline substances that are readily soluble in water. Many insoluble alkaloids (e.g. quinine and atropine) are used medicinally in the form of soluble salts. If alkali (sodium hydroxide) is added to solutions of such salts the free amine is liberated. Hexamethylenediamine used in the manufacture of nylon-6,6 is prepared by catalytic addition of hydrogen to nitriles. Aromatic amines also exist, such as phenylamine, which are important for the production of diazonium salts. They dissociate in water (some very weakly). Aromatic amines are much weaker bases than the aliphatics. One of the most important aromatic amines is aniline; pale brown liquid boiling at 184 C, melting at -6 C. Aniline is obtained commercially from chlorobenzene by heating with ammonia in the presence of copper catalyst or from a product of coal tar (nitrobenzene) through the reduction reaction. Aniline ids the starting material in the dye manufacturing industry and as in the manufacture of others. Aniline is converted into sulfanilic acid which is the parent compound of the sulfa drugs. Diphenylamine ( N-Phenyl Aniline) can be selected also as the important aromatic amine. It is a white to yellowish crystals; sparingly soluble in water; melting point 54 C. It is used as a neutralizing agent or stabilizer to make storage period longer against acid and chlorine; used as an additive in propellants, explosives, rubbers, plastics and lubricant. Aniline and Diphenylamine are important in the manufacture of rubber-processing chemicals, antioxidants and varnishes. Chemically modified amine products take part in many kinds of chemical reactions and offer many applications in the wide range of industrial fields include agrochemicals, dyestuffs, pharmaceuticals, and corrosion inhibitors. | ||
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