METHALLYL CHLORIDE

PRODUCT IDENTIFICATION

CAS NO. 563-47-3

METHALLYL CHLORIDE

EINECS NO. 209-251-2
FORMULA ClCH2(CH3)C=CH2
MOL WT. 90.55

H.S. CODE

2903.29

TOXICITY

Oral rat LD50: 848 mg/kg
SYNONYMS 3-Chloro-2-methylpropene; gamma-Chloroisobutylene;
beta-Methallyl chloride; Isobutenyl chloride; Methylallyl chloride; 2-Methyl-2-propenyl chloride; 2-Methylallyl chloride; 3-Chloro-2-methyl-1-propene; 3-Chloro-2-methylpropene-1; beta-Methylallyl chloride; Chlorure de methallyle; 2-Methyl-allylchlorid (German); 3-Chlor-2-methyl-prop-1-en (German); 3-Cloro-2-metil-prop-1-ene (Italian); Chlorure De Methallyle (French); Cloruro Di Metallile (Italian);
SMILES

 

CLASSIFICATION

 

PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL STATE clear liquid
MELTING POINT -80 C
BOILING POINT 71 - 72 C
SPECIFIC GRAVITY 0.926 - 0.930
SOLUBILITY IN WATER Insoluble
pH 6 - 7
VAPOR DENSITY 3.12

REFRACTIVE INDEX

1.4278
AUTOIGNITION

540 C

NFPA RATINGS Health: 2 Flammability: 3 Reactivity: 1
FLASH POINT -12 C
STABILITY

Stable under ordinary conditions

APPLICATIONS

Allyl- is the prefix for the univalent organic group, -CH2=CHCH2. Allyl alcohol is an example, CH2=CHCH2OH, clear, pungent liquid, boiling at 96 C; soluble in water. It is prepared from allyl chloride by hydrolysis. Allyl compound, an alkene hydrocarbon, has a vinyl group, CH2=CH-, attached to a methylene -CH2. Because of the highly reactive double bond, allyl can undergo free radical addition to double bond which readily combine with themselves or other monomers to form homopolymers or co-polymers which are used in the production of coatings, adhesives and elastomers. In addition to free radical addition, allyl compounds can participate in a wide variety of reactions including electrophilic additions, allylic substitution and oxidation.  Allyl, an unsaturated bond, imparts a characteristic odor in some compounds. An example is allyl isothiocyanate which is the main ingredient of black mustards. (white mustard consists principally of p-hydroxybenzyl isothiocyanate). Allyl isothiocyanate is called mustard oil. Allyl esters are involved in fragrance, flavor, or odor.

Methallyl chloride is used as an intermediate for organic synthesis especially for the manufacturing insecticide and fumigant. It is also used in the production of acrylics to improve dying property. It is also used as an intermediate for pharmaceuticals.

SALES SPECIFICATION

APPEARANCE

clear liquid

ASSAY

98.0% min

WATER

0.5% max

pH

6 - 7

TRANSPORTATION
PACKING

180kgs in drum

HAZARD CLASS 3 (Packing Group: II)
UN NO. 2554
REMARKS
Hazard Symbols: F+ N, Risk Phrases:12/20/22/43/51/53, Safety Phrases: 9/16/26/28A/36/37/39/45/61