AMMONIUM BISULFITE

PRODUCT IDENTIFICATION

CAS NO. 10192-30-0

AMMONIUM BISULFITE

EINECS NO. 233-469-7
FORMULA NH4HSO3
MOL WT. 99.10

H.S. CODE

 
TOXICITY  
SYNONYMS Ammonium bisulfite; Sulfurous acid monoammonium salt;
Ammoniumhydrogensulfit; Hidrogenosulfito de amonio; Hydrogénosulfite d'ammonium; Acid ammonium sulfite; Ammonium acid sulfite; Ammonium hydrogen sulfite; Ammonium hydrosulfite; Ammonium monosulfite; Ammonium sulfite hydrogen; Monoammonium sulfite; Ammonium hydrogensulphite;
SMILES [S](=O)(=O)[O-].[NH4+]

CLASSIFICATION

 

EXTRA NOTES

 

PHYSICAL AND CHEMICAL PROPERTIES (60% Solution))

PHYSICAL STATE clear to amber liquid
MELTING POINT -30 C
BOILING POINT  
SPECIFIC GRAVITY 1.31 - 1.35
SOLUBILITY IN WATER Soluble
pH 5
VAPOR DENSITY  

AUTOIGNITION

 

NFPA RATINGS

Health: 2; Flammability: 0; Reactivity: 0

REFRACTIVE INDEX

 

FLASH POINT  
STABILITY Stable under ordinary conditions. Hygroscopic.

EXTERNAL LINKS & GENERAL DESCRIPTION

Wikipedia Linking

Hazardous Substance Fact Sheet

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Pure ammonium bisulfite is a white crystalline solid. Commercially, however, aqueous liquid form (typically 60%) is common. Ammonium bisulfite's reductive and sulfonating properties provide versatile applications. It is used as an oxygen scavenger to eliminate the dissolved oxygen in waste water and in pipes. Ammonium bisulfite is a reductive bleaching agent. It reduces carbonyl and alcohol groups, which function as colorants of the substances. It is used in bleaching mechanical paper pulp, cotton, wool and kaolin clay. Additional applications include as a preservative (antioxidant) and a hair waving agent. Ammonium bisulfite is used in industries concerned with leather processing, food and beverage processing, gas purification, water treatment to remove excess chlorine, textiles and pulp processing, and many others. It is used as a reducing agent in chemical manufacturing. It is an alternative to sulfur dioxide  which is used in sterlization of equipment.

SALES SPECIFICATION

60% AQ. SOLUTION

ASSAY

59.0 - 61.0%

SPECIFIC GRAVITY

1.31 - 1.35

pH

4.5 - 5.5

TRANSPORTATION

PACKING  
HAZARD CLASS 8 (Packing Group: III)
UN NO. 2963

OTHER INFORMATION

Sulfate (also spelled sulphate in Europe) is any chemical compound containing the SO42- ion related to sulfuric acid (H2SO4). Sulfates are salts or esters of sulfuric acid, formed by replacing one or both of the hydrogens with a metal or a radical as in sodium sulfate, Na2SO4. Sulfates in which both hydrogens are replaced are called normal sulfates. Bisulfate is a compound that has the HSO4- radical. Bisulfate (called also hydrogen sulfate or acid sulfate) is a compound formed by replacing only one hydrogen in sulfuric acid. Sulfite (also sulphite) is a compound that contain the sulfite ion SO32-. Sulfites are salts or esters of sulfurous acid (H2SO3), formed by replacing one or both of the hydrogens with a metal or a radical as in sodium sulfite, Na2SO3. Sulfites in which both hydrogens are replaced are called normal sulfites. Bisulfite is a compound that has the HSO3- radical. Bisulfate (called also hydrogen sulfite or acid sulfite) is a compound formed by replacing only one hydrogen in sulfurous acid. The term of 'meta' or 'pyro' is the chemical prefix for oxo acid formed through the loss of one water molecule (dehydration) from two molecules of ortho acid by heating. Pyrosulfuric acid is an example ( 2H2SO4 - H2O = H2S2O7). Ortho acid is the compound fully hydrated acid or its salts. Orthophosphoric acid is an example (H3PO4 = P2O5.3H2O), in contrast to the less hydrated form, pyrophosphoric acid (HPO3 = P2O5.H2O). Na2O5S2 is called sodium metabisulfite (2·HNaO3S - H2O). Sulfide is a compound having one or more sulfur atoms in which the sulfur is connected directly to a carbon, metal, or other nonoxygen atom; for example sodium sulfide, Na2S. Sulfide ion is S2- with oxidation number -2. Bisulfide ion is an anion formed by two sulfur atoms having an overall -2 charge, (S2)2-. Sulfamate is a salt of sulfamic acid (HSO3NH2). Calcium sulfamate Ca(SO3NH2)2 is an example.