(S)-(-)-1,1'-BI-2-NAPHTHOL

PRODUCT IDENTIFICATION

CAS NO. 18531-94-7

(S)-(-)-1,1'-BI-2-NAPHTHOL

EINECS NO.

 

FORMULA C20H14O2
MOL WT. 286.33

H.S. CODE

 

TOXICITY

 

SYNONYMS S-(-)-2,2'-Dihydroxy-1,1'-dinaphthyl;
(S)-(-)-1,1'-Binaphthalene-2,2'-diol; (S)-Binol; (-)-2,2'-Dihydroxy-1,1'-dinaphthyl;

DERIVATION

 

CLASSIFICATION

 

PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL STATE

off-white crystals

MELTING POINT 205 - 211 C
BOILING POINT  
SPECIFIC GRAVITY  
SOLUBILITY IN WATER  
pH  
VAPOR DENSITY

 

AUTOIGNITION

 

NFPA RATINGS

Health: 2 Flammability: 0 Reactivity: 0

REFRACTIVE INDEX

 
FLASH POINT

 

STABILITY

Stable under ordinary conditions. Hygroscopic.

GENERAL DESCRIPTION

An effective chiral auxiliary used in the catalytic asymmetric oxidation of sulfides to sulfoxides. Derivatives of binaphthol are used in asymmetric rearrangements, epoxidations.reductions.

SALES SPECIFICATION

APPEARANCE

off-white crystals

CHEMICAL PURITY

99.5% min

OPTICAL PUIRTY

99.5% min e.e.
TRANSPORTATION
PACKING
 
HAZARD CLASS  
UN NO.  
OTHER INFORMATION
Hazard Symbols: XI, Risk Phrases: 36/37/38, Safety Phrases: 22-24/25
Optical Rotation: -
35° ~ -36° (C=1, THF)