|
UREA
|
|
PRODUCT
IDENTIFICATION
|
| CAS
NO. |
57-13-6 |

|
| EINECS
NO. |
200-315-5 |
| FORMULA |
H2NCONH2 |
| MOL
WT. |
60.06 |
|
H.S.
CODE
|
3102.10 |
| TOXICITY |
Oral
rat LD50: 8471 mg/kg |
| SYNONYMS |
Alphadrate;
Amide of carbonic acid; Carbamimidic acid; |
| Carbamide
resin; Carbamimidic acid; Carbonyl diamide; Carbonyldiamine;
Isourea; |
| DERIVATION |
Ammonia,
Carbon Dioxide |
|
CLASSIFICATION
|
|
|
GENERAL
DESCRIPTION
|
|
UREA
(also called CARBAMIDE)
is the diamide of carbonic acid. It is a colourless,
crystalline substance that melts at 132.7º
C and decomposes before boiling. Urea has important
uses as a fertilizer and feed supplement, as well
as a starting material for the manufacture of plastics
and drugs. Urea is prepared commercially in vast
amounts from liquid ammonia and liquid carbon dioxide.
These two materials are combined under high pressures
and elevated temperatures to form ammonium carbamate,
which then decomposes at much lower pressures to
yield urea and water. Because its nitrogen content
is high and is readily converted to ammonia in the
soil, urea is one of the most concentrated nitrogenous
fertilizers. An inexpensive compound, it is incorporated
in mixed fertilizers as well as being applied alone
to the soil or sprayed on foliage. With formaldehyde
it gives methylene-urea fertilizers, which release
nitrogen slowly, continuously, and uniformly, a
full year's supply being applied at one time. Although
urea nitrogen is in nonprotein form, it can be utilized
by ruminant animals (cattle, sheep), and a significant
part of these animals' protein requirements can
be met in this way. The use of urea to make urea-formaldehyde
resin is second in importance only to its use as
a fertilizer. Large amounts of urea are also used
for the synthesis of barbiturates. Urea reacts with
alcohols to form urethanes and with malonic esters
to give barbituric acids. With certain straight-chain
aliphatic hydrocarbons and their derivatives, urea
forms crystalline inclusion compounds, which are
useful for purifying the included substances.
|
|
PHYSICAL
AND CHEMICAL PROPERTIES
|
| PHYSICAL
STATE |
odorless
white powder, prill, pearl, granular. |
| MELTING
POINT |
132
- 135 C
|
| BOILING
POINT |
Decomposes |
| SPECIFIC
GRAVITY |
1.32
- 1.34 |
| SOLUBILITY
IN WATER |
Soluble |
| pH |
Basic |
| VAPOR
DENSITY |
2.07 |
|
AUTOIGNITION
|
|
|
NFPA
RATINGS
|
Health:
1; Flammability: 0; Reactivity: 0 |
|
REFRACTIVE
INDEX
|
|
| FLASH
POINT |
|
| STABILITY |
Stable
under ordinary conditions |
|
APPLICATIONS
|
|
Fertilizer,
Urea-Formaldehyde, Melamine,
Feed
Supplement, Plastics, Drugs, Barbiturates, Hydrazine, Stabilizer
of explosive, oil field, fire-proof, viscosity
control, dying, paint. adhesives.
|
| SALES
SPECIFICATION |
|
FERTILIZER
GRADE
|
|
PROPERTY
|
UNIT
|
PRILLED
|
GRANULAR
|
|
APPEARANCE
|
|
White free-flowing
Prilled
|
White
free-flowing
granules
|
|
TOTAL
NITROGEN
|
wt%
min
|
46.2
|
46.2
|
|
BIURET
|
wt%
max
|
1.0
|
1.0
|
|
MOISTURE
|
wt%
max
|
0.3
|
0.5
|
|
FREE
AMMONIA
|
ppm
max
|
150
|
160
|
|
IRON
|
ppm
max
|
0.5
|
5
|
|
PH
|
20%
sol.
|
9.50
~ 10
|
|
|
TURBIDITY
|
20%
sol.
|
1.0
~ 5.0
|
|
|
PARTICLE
DISTRIBUTION
|
%
|
>2.8mm
|
<
1
|
>
4.0mm
|
<
3
|
|
2.8~2.0mm
|
20~35
|
2.0~4.0mm
|
95
|
|
2.0~1.6mm
|
35~55
|
1.0~2.0mm
|
2~4
|
|
1.6~1.4mm
|
10~25
|
<1.0mm
|
<
1
|
|
1.4~1.0mm
|
10~15
|
|
|
|
<1.0mm
|
<
1
|
|
|
|
|
PRICE
INDICATION
|
|
|
|
INDUSTRIAL
GRADE
|
|
APPEARANCE
|
white
spherical particle |
|
UREA
|
99.0%
min |
|
WATER
|
0.5%
max |
|
pH
|
11
(10% sol.) |
|
TRANSPORTATION
|
| PACKING |
25kgs,
50kgs, 1mt in Bag |
| HAZARD
CLASS |
Not
regulated |
| UN
NO. |
|
| GENERAL DESCRIPTION OF FERTILIZERS |
Fertilizer is a material that is added to the soil to supply one or more
elements required for plant growth and productiveness. The major three elements
are nitrogen, potassium and phosphorus), the secondary elements are calcium,
sulfur, magnesium, and other elements are boron, manganese, iron, zinc, copper
and molybdenum. Fertilizers enhance the natural fertility of the soil or replace
the chemical elements taken from the soil by harvesting, grazing, leaching or
erosion. Organic fertilizers include poperly managed barnyard manure, compost
and green manure. Manure contains nitrogen and phosphate content. It is
sometimes modified with superphosphate to make it a better balanced fertilizer.
Compost, decayed to a relatively stable, amorphous state, is made from plant
materials mixed with manure and some soil. Green manure is a herbaceous plant
material plowed into the soil that has not undergone decay. Artificial
fertilizers are inorganic fertilizers formulated in appropriate concentrations
and combinations supply three main nutrients: nitrogen, phosphorus and potassium
(N, P and K) for various crops and growing conditions. N (nitrogen) promotes
leaf growth and forms proteins and chlorophyll. P (phosphorus) contributes to
root, flower and fruit development. K (potassium) contributes to stem and root
growth and the synthesis of proteins. The common inorganic fertilizers include
ammonia (82% nitrogen), NPK combinations, urea (46% nitrogen), superphosphate,
mono and dibasic ammonium phosphates (containing nitrogen and phosphate),
calcium ammonium nitrate, potassium chloride (muriate of potash).
|
Fertilizer |
Nutrient
wt %
|
|
N |
P2O5 |
K2O |
| Ammonia
anhydrous |
82 |
|
|
| Ammonia
solution |
20
- 25 |
|
|
| Ammonium Bicarbonate |
15.5
|
|
|
| Ammonium Chloride |
25
-27
|
|
|
| Ammonium
Phosphate sulfate |
13
- 16 |
20
- 39 |
|
| Ammonium
Polyphosphate |
10
- 11 |
34
- 37 |
|
| Ammonium
Thiosulfate |
12 |
|
|
| Ammonium Chloride |
25
- 26 |
|
|
| Ammonium Nitrate |
33
- 34 |
|
|
| Ammonium Sulfate |
21 |
|
|
| Ammonium Sulfate Nitrate |
26
|
|
|
| Calcium Ammonium Nitrate |
20
- 28
|
|
|
| Calcium Cyanamide |
20
- 21
|
|
|
| Calcium
Nitrate |
15 |
|
|
| Diammonium Phosphate |
18
- 21 |
46
- 54 |
|
| Dicalcium phosphate |
|
35
- 52
|
|
| Kainit |
|
|
12
- 22
|
| Monoammonium Phosphate |
11 |
48
- 55 |
|
| Nitrogen Solution |
28
- 41
|
|
|
| Phosphate Rock |
|
26
- 37
|
|
| Potassium Chloride |
|
|
60 |
Potassium Magnesium Sulfate
|
|
|
22
|
| Potassium Nitrate |
13 |
|
44 |
Potassium Sulfate
|
|
|
50
|
| Slag Basic |
|
12
- 18
|
|
|
Slag
Potassic
|
|
|
43
|
| Superphosphate single |
|
17
- 20
|
|
| Superphosphate triple |
|
44
- 48
|
|
| Sodium
Nitrate |
16 |
|
|
| Urea Phosphate |
17 |
43
- 44 |
|
| Urea |
45 |
|
|
| Urea
Ammonium Nitrate |
28
- 32 |
|
|
| Urea
Ammonium Phosphate |
21
- 38 |
13-42 |
|
| Urea
Sulfate |
30
- 40 |
|
|
|
|