Caustic
soda; Sodium hydrate; soda lye; Lye; Sodium
Hydroxide
White
Caustic; Caustic Flake; Hydroxyde De Sodium (French);
Natriumhydroxid (German); Natriumhydroxyde (Dutch);
Sodio(Idrossido Di);
RAW
MATERIALS
CLASSIFICATION
GENERAL
DESCRIPTION
Sodium
Hydroxide, commonly known as caustic soda,
lye, or sodium hydrate, is a caustic compound which
attacks organic matter. (caustic soda is sodium
hydroxide, caustic potash is potassium hydroxide
and silver nitrate is lunar caustic.) Caustic soda
is available commercially in various white solid
forms and as a solutions of various concentrations
in water. It is very soluble in water, alcohol,
and glycerin and absorbs carbon dioxide and moisture
from the air. Sodium hydroxide is prepared by the
reaction of sodium carbonate (soda) in concentrated
solution form with calcium hydroxide (slaked lime).
But the principal method for its manufacture
is by the electrolysis of brine. (the two current
technologies are the diaphragm and the membrane).
The electrolyte is saturated brine (about 25% aqueous
sodium chloride). The chloride ion is oxidized at
the anode to chlorine gas. chlorine gas is a coproduct.
Sodium hydroxide is a strong base and inexpensive
which find many applications in the chemical industry.
Sodium hydroxide provides fuctions of neutralisation
of acids, hydrolysis, condensation. saponification
and replacement of other groups in organic compounds
of hydroxyl ions. The major use of sodium hydroxide
is as a chemical and in the manufacture of other
chemicals. It is used in textile industry. Sodium
hydroxide is used mainly for two processes in textile
manufacture. Mercerizing of fibre with sodium and
hydroxide solution enables greater tensional strength
and consistent lustre. It also removes waxes and
oils from fibre to make the fibre more receptive
to bleaching and dying. Sodium hydroxide is also
used in the production of viscose rayon. Cellulose
is extracted from pulp using sodium hydroxide and
subsequently treated with high purity sodium hydroxide
to produce soda cellulose. Further chemical
treatment results in a rayon fibre. This is a declining
market due to the competition from synthetic (ie
petrochemical) fibres. It is used in making paper
and pulp.Sodium hydroxide aids separation of cellulose
fibres from lignin; this breaks down wood into pulp.
Sodium hydroxide also helps bleach paper to required
whiteness and brightness. In alumina production
industry, a strong alkali solution separates pure
alumina from bauxite ore. Alumina is then recovered
through precipitation and finally, calcination.
Sodium hydroxide is also widely used in in making
soaps and detergents, Sodium hydroxide was originally
used for soap manufacture, but now has a wider variety
of functions. As well as an extractant and refining
agent for certain oils, sodium hydroxide is used
to produce active agents, or builders in modern
synthetic detergents. Sodium Hydroxide is used for
sodium hypochlorite which is used as a household
bleach and disinfectant and for sodium phenolate
used in antiseptics and for the manufacture of Aspirin.
PHYSICAL
AND CHEMICAL PROPERTIES
PHYSICAL
STATE
White,
deliquescent pellets or flakes
MELTING
POINT
318
C
BOILING
POINT
1390
C
SPECIFIC
GRAVITY
2.13
SOLUBILITY
IN WATER
pH
13
- 14 (0.5% sol.)
VAPOR
DENSITY
AUTOIGNITION
NFPA
RATINGS
Health:
3; Flammability: 0; Reactivity: 1
REFRACTIVE
INDEX
FLASH
POINT
Not
considered to be a fire hazard
STABILITY
Stable
under ordinary conditions
APPLICATIONS
Direct
application,(pulp and paper, soaps and detergents,
aluminia, petroleum, textiles, water treatment,);
organic chemicals, (propylene oxide, polycarbonate,
ethyleneamines, epoxy resins,); inorganic chemicals,
(sodium/calcium hypochlorite, sulfur-containing
compounds, sodium cyanide, )